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National
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Reacting to chemical reactions
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Many cleaners and spotters run into
spotting problems because they do not understand chemical
reactions and what to do.
Chemical reactions can not only affect
the fabric and dye but also staining as well. When a chemical
reaction occurs there are proper steps to take.
Reactions
Salt residue. Acids and alkali neutralize each other,
producing water and salt. The salt residue produces a white
staining that may not flush out easily.
Correction. Use any mild detergent for
breaking up the salt residue and flush through using a water
gun and steam.
Alkaline color change. Alkali can cause a color change on many fabrics
especially wool and silk.
Correction. The chemical producing the
color change should be thoroughly flushed. It should then be
neutralized with a mild acid, such as acetic or tannin formula.
Acid color change. Many fabrics are sensitive to acids, especially
cotton, rayon and linen.
Correction. Flush area thoroughly and
apply a mild alkali such as ammonia or protein formula.
Chemical reactions on stains
Mustard. There
are ingredients in mustard that react to alkali, such as
ammonia. The staining can turn purple. This is an indication
that a wrong chemical is being used and the stain is oxidizing.
Solution. Flush area and work stain out
using acids and tannin formula. The last step would involve
using oxidizing bleaches such as hydrogen peroxide and sodium
hypochlorite.
Red cabbage. In the presence of an alkali, you will
find that the staining turns pink or red and in the presence of
an acid it will turn green. Red cabbage and similar stains
react similar to litmus paper. When the staining is turning red
it is indicating that the stain is being set.
Solution. Flush area thoroughly and work
stains with acids. Oxidizing bleaches will probably be
necessary to remove last traces.
Iodine. You
may find an iodine stain turning blue-black when contacting a
fabric. This is an indication that there is starch in the
fabric.
Solution. The best and safest way to
reduce and remove iodine staining is using sodium thiosulphate.
Albuminous and protein staining. In the presence of alcohol it will
permanently set and oxidize this type of staining. This can
occur when oily type paint remover is used on the staining and
steam is applied. This causes the alcohol in the oily type
paint remover to be activated.
Also, general formula should never be
used on this type of staining.
Bleach reactions
Sodium perborate and sodium percarbonate. These bleaches may cause a color change
due to the fact that they are alkaline in nature.
Solution. They should be rinsed and
neutralized with an acid.
Sodium hypochlorite. When this bleach contacts a white wool or silk,
a yellow discoloration will occur.
Solution. The bleach should be thoroughly
rinsed from the fabric and neutralized using a reducing bleach
such as sodium hydrosulphite or sodium bisulphate.
Flush the area thoroughly before applying
the reducing bleach.
Potassium permanganate. This bleach is found in some ink removers. It
usually leaves a brown discoloration that cannot be flushed
out.
Solution. The best way to reduce the
discoloration is using hydrogen peroxide and acetic acid.
Sodium hydrosulphite. This can leave a streaking on some fabrics.
Solution. Hydrogen peroxide plus ammonia.
Titanium sulphate. This is a very complex
bleach and different discolorations can occur.
This bleach also reacts with other
chemicals producing a number of reactions. It is sensitive
enough to pick up the presence of a chemical even after it has
been flushed from the fabric.
Titanium plus peroxide causes a yellow
area. Titanium plus ammonia causes a black area.
Solution. This discoloration can be
removed using rust remover. The rust remover used must contain
hydrofluoric acid.
Sometimes the titanium stripper may cause
a color change due to its acid nature. In this case, the area
must be flushed thoroughly and ammonia must be used to
neutralize it. Titanium on some wools may leave a gray residue.
In that case hydrogen peroxide should be used.
Trial and error will often determine the
best solution to the problem.
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