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Cationic detergents in wetcleaning
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Years back wetcleaning was a very minor phase of the drycleaning process. The
drycleaner was taught to remove wetside stains on wetcleanable items by using
the moisture batch run in the drycleaning machine.
In this process water, detergent and solvent were emulsified in the wheel of the
drycleaning machine and garments were batched to remove stains and soil. This
process was very effective for stains and soil.
As time passed and EPA stepped in regulating solvents, the need for wetcleaning
became important. The problem was, however, that the wetcleaning detergents
were not effective on silks, wools and other fabrics where wrinkling, shrinking
and feel were factors.
As a professional garment analyst, I was called upon to develop wetcleaning
courses and procedures that drycleaners could turn to. I have a very strong
relationship with many of the major chemical companies. Some of these companies
are Metro Chem, Laidlaw, Stanford and others.
These companies develop cationic detergents that I received for testing. I did
extensive comparison testing on many fabrics using the new technology versus
the old.
The new cationic detergents gave the cleaner the ability to wetclean wools,
silks, rayon and other fabrics with proper feel, luster and reduced shrinkage.
Manufacturers then improved wetcleaning technology with sophisticated
wetcleaning machines, dryers and tensioning equipment. This increased the
cleaners ability to wetclean more fabrics safely. The drycleaner at one time
did less than 1 percent wetcleaning and now has the capability to wetclean 45
to 65 percent of their garments.
Wetcleaning technology is constantly improving and I recently had the
opportunity to test the advanced technology of the cationic detergents
manufactured by Cleaners Chemical Corp.
What are cationic detergents
Cationic detergents are a classification of detergents with positive ions that
have an ability to clean and emulsify soil. They have an ability to stay with
the fabric and produce a softer fabric. Many of them contain enzymes which
remove soil and stains safely. They are often chemically slightly acid in
nature, different from the alkalinity of
built detergents.
How cationic detergents work
The ability to control shrinkage in fabrics means that the detergent should act
as a coating on the yarns. For example wool is a fiber which has scales that
tend to interlock and mat when subjected to mechanical action and friction.
The cationic detergent coats the yarn which helps reduce the ability of the yarn
to mat and shrink. This can be visualized if we picture the yarn as a
telescope. If the telescope is lubricated it will readily slide up and down.
Cationic detergents also have a strong affinity for the fabric and some of it
stays with the fabric even when rinsed. The acid content of the detergent will
aid in setting colors, softening fabrics and helping to prevent shrinkage.
Shrinkage is increased by the alkalinity of a detergent. Cottons, linens and
other fabrics also can be wetcleaned with less shrinkage, reduced wrinkling,
and softer feel and hand. The reasons why anionic detergents do not work as
well is because they do not coat the yarn nor stay with the fabric.
Limitations of cationic detergents
Cationic detergents do not clean as well as anionic detergents, which means that
heavily soiled garments should be cleaned using anionic detergents. Detergents
with an alkalinity will also have a better cleaning action than acid based
detergents.
Cationic detergents will affect glued on trimmings. Spandex yarns may weaken
when using cationic detergents, also.
Ski jackets and coated fabrics may streak and form swales using cationic
detergents.
Cationic detergents can not be used in conjunction with anionic detergents. For
example, if you pre-spot a garment using anionic detergents and clean with
cationics it will break down and form rings.
How to use
Cationic agents work best on silk, wool, angora and wetcleanable rayon. They are
also used on hard-finished fabrics when softening of the fabric is important.
Classify garments using wetcleanable cycles with minimum mechanical action.
Additional softening agents can be used since most softening agents are
cationic in nature and will not affect the detergent.
A short drying cycle should be used after wetcleaning to activate the cationic
detergent or softening agent. Wools and angoras should not be dried for more
than three minutes.
Special offer
My wetcleaning manual, “The Art of Wetcleaning,” is available for purchase. Cleaners Chemical Corp and Laidlaw Chemical will
send samples of their wetcleaning products to anyone purchasing my manual.
Contact me at the phone or e-mail address below.
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